CHEBI:60052 - siroheme(8−)

Main ChEBI Ontology Automatic Xrefs Reactions Pathways Models
ChEBI Name siroheme(8−)
ChEBI ID CHEBI:60052
ChEBI ASCII Name siroheme(8-)
Definition A cyclic tetrapyrrole anion obtained by deprotonation of the carboxy groups of siroheme; major species at pH 7.3.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Kristian Axelsen
Supplier Information
Download Molfile XML SDF
Formula C42H36FeN4O16
Net Charge -8
Average Mass 908.59700
Monoisotopic Mass 908.15196
InChI InChI=1S/C42H46N4O16.Fe/c1-41(17-39(59)60)23(5-9-35(51)52)29-14-27-21(11-37(55)56)19(3-7-33(47)48)25(43-27)13-26-20(4-8-34(49)50)22(12-38(57)58)28(44-26)15-31-42(2,18-40(61)62)24(6-10-36(53)54)30(46-31)16-32(41)45-29;/h13-16,23-24H,3-12,17-18H2,1-2H3,(H10,43,44,45,46,47,48,49,50,51,52,53,54,55,56,57,58,59,60,61,62);/q;+2/p-10/t23-,24-,41+,42+;/m1./s1
InChIKey DLKSSIHHLYNIKN-QIISWYHFSA-D
SMILES C[C@]1(CC([O-])=O)[C@H](CCC([O-])=O)C2=CC3=[N+]4C(=Cc5c(CC([O-])=O)c(CCC([O-])=O)c6C=C7C(CCC([O-])=O)=C(CC([O-])=O)C8=[N+]7[Fe--]4(N2C1=C8)n56)[C@@H](CCC([O-])=O)[C@]3(C)CC([O-])=O
Metabolite of Species Details
Saccharomyces cerevisiae (NCBI:txid4932) Source: yeast.sf.net See: PubMed
Roles Classification
Biological Role(s): Saccharomyces cerevisiae metabolite
Any fungal metabolite produced during a metabolic reaction in Baker's yeast (Saccharomyces cerevisiae ).
cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
(via porphyrins )
metabolite
Any intermediate or product resulting from metabolism. The term 'metabolite' subsumes the classes commonly known as primary and secondary metabolites.
(via heme )
prosthetic group
A tightly bound, specific nonpolypeptide unit in a protein determining and involved in its biological activity.
(via heme )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing siroheme(8−) (CHEBI:60052) has role Saccharomyces cerevisiae metabolite (CHEBI:75772)
siroheme(8−) (CHEBI:60052) has role cofactor (CHEBI:23357)
siroheme(8−) (CHEBI:60052) is a cyclic tetrapyrrole anion (CHEBI:58941)
siroheme(8−) (CHEBI:60052) is a heme (CHEBI:30413)
siroheme(8−) (CHEBI:60052) is conjugate base of siroheme (CHEBI:28599)
Incoming siroheme (CHEBI:28599) is conjugate acid of siroheme(8−) (CHEBI:60052)
IUPAC Name
[3,3',3'',3'''-[(7S,8S,12S,13S)-3,8,13,17-tetrakis(carboxymethyl)-8,13-dimethyl-7,8,12,13-tetrahydroporphyrin-2,7,12,18-tetrayl-κN21,κN22,κN23,κN24]tetrapropanoato(10−)]ferrate(6−)
Synonyms Sources
siroheme UniProt
siroheme hexaanion ChEBI
Last Modified
26 July 2019