CHEBI:64668 - geranylgeranyl-chlorophyll a

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ChEBI Name geranylgeranyl-chlorophyll a
ChEBI ID CHEBI:64668
ChEBI ASCII Name geranylgeranyl-chlorophyll a
Definition A chlorophyll that is the ester obtained by formal condensation between the carboxy group of chlorophyllide a and the hydroxy group of geranylgeraniol.
Stars This entity has been manually annotated by the ChEBI Team.
Submitter Rebecca Foulger
Supplier Information ZINC000096077692
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Formula C55H66MgN4O5
Net Charge 0
Average Mass 887.44130
Monoisotopic Mass 886.48836
InChI InChI=1S/C55H67N4O5.Mg/c1-13-39-35(8)42-28-44-37(10)41(24-25-48(60)64-27-26-34(7)23-17-22-33(6)21-16-20-32(5)19-15-18-31(3)4)52(58-44)50-51(55(62)63-12)54(61)49-38(11)45(59-53(49)50)30-47-40(14-2)36(9)43(57-47)29-46(39)56-42;/h13,18,20,22,26,28-30,37,41,51H,1,14-17,19,21,23-25,27H2,2-12H3,(H-,56,57,58,59,61);/q-1;+2/p-1/b32-20+,33-22+,34-26+;/t37-,41-,51+;/m0./s1
InChIKey DLGTYWBJNMHIPY-JYVCQAQSSA-M
SMILES CCC1=C(C)C2=Cc3c(C=C)c(C)c4C=C5[C@@H](C)[C@H](CCC(=O)OC\C=C(/C)CC\C=C(/C)CC\C=C(/C)CCC=C(C)C)C6=[N+]5[Mg--]5(n34)n3c(=CC1=[N+]25)c(C)c1C(=O)[C@H](C(=O)OC)C6=c31
Roles Classification
Biological Role(s): cofactor
An organic molecule or ion (usually a metal ion) that is required by an enzyme for its activity. It may be attached either loosely (coenzyme) or tightly (prosthetic group).
(via porphyrins )
View more via ChEBI Ontology
ChEBI Ontology
Outgoing geranylgeranyl-chlorophyll a (CHEBI:64668) has functional parent (E,E,E)-geranylgeraniol (CHEBI:46762)
geranylgeranyl-chlorophyll a (CHEBI:64668) has functional parent chlorophyllide a (CHEBI:16900)
geranylgeranyl-chlorophyll a (CHEBI:64668) is a carboxylic ester (CHEBI:33308)
geranylgeranyl-chlorophyll a (CHEBI:64668) is a chlorophyll (CHEBI:28966)
IUPAC Name
[methyl (3S,4S,21R)-14-ethyl-4,8,13,18-tetramethyl-20-oxo-3-(3-oxo-3-{[(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl]oxy}propyl)-9-vinylphorbine-21-carboxylatato(2−)-κ4N23,N24,N25,N26]magnesium
Synonyms Sources
[methyl (3S,4S,21R)-14-ethyl-4,8,13,18-tetramethyl-20-oxo-3-(3-oxo-3-{[(2E,6E,10E)-3,7,11,15-tetramethylhexadeca-2,6,10,14-tetraen-1-yl]oxy}propyl)-9-vinylphorbine-21-carboxylatato(2−)-κ4N,N']magnesium ChEBI
geranylgeranyl-chl a SUBMITTER
geranylgeranyl-chlorophyllide a ChEBI
GG-chl a SUBMITTER
GG-chlorophyll a SUBMITTER
Manual Xref Database
CPD-7005 MetaCyc
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Citations Types Sources
6249390 PubMed citation Europe PMC
9492312 PubMed citation Europe PMC
IND43633051 Agricola citation Europe PMC
Last Modified
09 February 2016